Most insulated shells are what, 60g of syn?
So to get to 200g, you add something like the Cerium LT?
My insulated shell is 140gm. As Neononrchid suggests, you need to try some of this out yourself. The trouble with suggesting an item of clothing is that everyone is different. We don't even know if Arcteryx will be a good fit for you, some of their pieces are too trim for me. I will however make the following suggestions:
You run cold and are struggling to find something for colder weather. Don't waste too much time or money on 60gm or equivalent pieces unless they are cheap, this goes for midlayers or insulated shells. Fleece can often be a cheaper, better alternative for those pieces. Preferences vary but based on your comments you do seem to need built up closer to 200gm (or equivalent) total.
Back off from the high end alpine oriented stuff unless you really like a specific piece. Not only are you paying for features you do not need, it may be features you don't like. For example, for me the 10 denier fabric on the Cerium LT is a deal breaker. It does however look like the sort of piece the ultralight backpacking guys will love, you may too. Downhill skiing is not as difficult to cater for as some other cold weather activities, the gear does not have to be expensive. I personally suggest the Atom AR
IF it is a good fit. It is cheaper and and a more all round piece (hence AR). Try it and some of the other suggestions you see here.
If you decide to get an insulated shell, no need to get expensive - you are looking for $20 of insulation packaged in a useful form. You can get a quality full waterproof breathable down skiing jacket for under $400 list price. You can go much cheaper too and still find good jackets. Personally I am going to try the Stio Durrance jacket based on the fact that Stio was founded by the old Cloudveil guys and I liked some of their old stuff. Based on previous experiences with online clothes shopping, there is a 50/50 chance I hate the jacket and send it back.
You need to decide how you feel about synthetics vs down. It is not just a technical issue, they have a very different feel when wearing them. That feel is also different when used as mid layer compared to an outer layer.