You can “cant” your bike shoes by placing a bit of duct tape under the inside heel and toe of your footbed. It does work. But if it “feels” too far out, don’t do it. We aren’t all perfectly aligned. (Inserting laughter at myself here). After tons of work by coaches on my track bike pedals (which were clipless, but could have no float or rotating movement whatsoever because that created loss of power in sprints), I learned that attempting to align knees perfectly can result in pain, or worse, injury.
Seems like one-legged pedaling would better serve you in developing quad musculature. Better yet, a fixed gear would do the trick.
You live near Boulder. Perfect place to ride a fixie.